By Alois Fuerstner

The great growth in olefin metathesis accomplished over the last decade can rarely be over priced. as a result of improvement of a brand new iteration of good outlined and high-performance organometallic catalysts, this response is quickly evolving into probably the most flexible instruments for complicated natural chemistry, typical product synthesis, advantageous chemical creation and polymer sciences. Written by means of the various best specialists during this box, this monograph intends to familiarize the reader with the main interesting advancements and frontiers during this flourishing box of chemistry examine.

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Extra resources for Alkene Metathesis in Organic Synthesis (Topics in Organometallic Chemistry) (Vol 1)

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38 A. Fürstner 5 Selected Applications of RCM to Target Oriented Synthesis . . . 6 Carbocyclic Nucleosides . . . . . . . . . . Manzamine A . . . . . . . . . . . . . Epothilone A . . . . . . . . . . . . . (+)-Lasiodiplodin . . . . . . . . . . . Tricolorin A . . . . . . . . . . . . . (-)-Gloeosporone: Development of a Binary Metathesis Catalyst System . . . . . . . . . . . . 6 . . . . . .

Bespalova NB, Bovina MA, Sergeeva MB, Zailin VG (1994) Russ Chem Bull 43:1425 193. Leconte M, Jourdan I, Pagano S, Lefebvre F, Basset JM (1995) J Chem Soc Chem Commun 857 194. Couturier JL, Leconte M, Basset JM (1993) Transition Metal Carbyne Com 392:39 195. Leconte M, Basset JM, Quignard F, Larroche C (1986) In: Braterman PS (ed) Reactions of coordinated ligands. Plenum, New York 196. Martinez LE, Nugent WA, Jacobsen EN (1996) J Org Chem 61:7963 197. Schmalz HG (1995) Angew Chem Int Ed Engl 34:1833 198.

They combine a high activity with an excellent tolerance towards polar functional groups and provide access to carbo- and heterocycles of almost any ring size by ring closing metathesis (RCM) of diene substrates. This includes even medium-sized and macrocyclic rings. The design and mode of action of these and related catalysts will be outlined and their performance will be illustrated by some selected applications to the synthesis of complex natural products. a. the allenylidene complexes 2), as well as recent advancements related to the use of supercritical carbon dioxide (scCO2) as reaction medium for RCM, will be discussed.

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Alkene Metathesis in Organic Synthesis (Topics in by Alois Fuerstner
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